Publications

Previous Work

Selected Publications

Taming the Chlorine Radical: Enforcing Steric Control over Chlorine-Radical-Mediated C–H Activation
Gonzalez, M. I.; Gygi, D.; Qin, Y.; Zhu, Q.; Johnson, E. J.; Chen, Y.-S.; Nocera, D. G. J. Am. Chem. Soc. 2022, 144, 1464–1472.

49

Capturing the Complete Reaction Profile of a C–H Bond Activation
Gygi, D.†; Gonzalez, M. I.†; Hwang, S. J.; Xia, K. T.; Qin, Y.; Johnson, E. J.; Gygi, F.; Chen, Y.-S.; Nocera, D. G. J. Am. Chem. Soc. 2021, 143, 6060–6064.

48

Confinement of Atomically-Defined Metal Halide Sheets in a Metal–Organic Framework
Gonzalez, M. I.†; Turkiewicz, A. B.†; Darago, L. E.; Oktawiec, J.; Bustillo, K.; Grandjean, F.; Long, G. J.; Long, J. R. Nature, 2020, 557, 64–68.

47

Separation of Xylene Isomers through Multiple Metal Site Interactions in Metal–Organic Frameworks
Gonzalez, M. I.†; Kapelewski, M. T.†; Bloch, E. D.; Hudson, M. R.; Reed, D. A.; Mason, J. A.; Milner, P. J.; Barin, G.; Brown, C. M.; Long, J. R. J. Am. Chem. Soc. 2018, 140, 3412–3422.

46

Structural characterization of framework–gas interactions in the metal–organic framework Co2(dobdc) by in situ single-crystal X-ray diffraction
Gonzalez, M. I.; Mason, J. A.; Bloch, E. D.; Teat, S. J.; Gagnon, K. J.; Morrison, G. Y.; Queen, W. L.; Long, J. R. Chem. Sci. 2017, 8, 4387–4398.

45

Ethylene Oligomerization in Metal–Organic Frameworks Bearing Nickel(II) 2,2′-Bipyridine Complexes
Gonzalez, M. I.; Oktawiec, J.; Long, J. R. Faraday Discuss. 2017, 201, 351–367.

44

Single-Crystal-to-Single-Crystal Metalation of a Metal–Organic Framework: A Route Toward Structurally Well-Defined Catalysts
Gonzalez, M. I.; Bloch, E. D.; Mason, J. A.; Teat, S. J.; Long, J. R. Inorg. Chem. 2015, 54, 2995–3005.

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†These authors contributed equally.

Additional Published Research

Electrophotocatalytic perfluoroalkylation by LMCT excitation of Ag(II) perfluoroalkyl carboxylates
Campbell, B. M.; Gordon, J. B.; Raguram, E. R.; Gonzalez, M. I.; Reynolds, K. G.; Nava, M.; Nocera, D. G. Science, 2023, 383, 279–284.

42

Oxidation Chemistry of Bicarbonate and Peroxybicarbonate: Implications for Carbonate Management in Energy Storage
Yan, Z.†; Reynolds, K. G.†; Sun, R.; Shin, Y.; Thorarinsdottir, A. E.; Gonzalez, M. I.; Kudisch, B.; Galli, G.; Nocera, D. G. J. Am. Chem. Soc. 2023, 145, 22213–22221.

41

Comparative excited state dynamics of metallo meso-(4-fluoro-2,6-dimethylphenyl) porphyrins
Crisp, W.†; Fagan-Avery, S. A.†; Campbell, B. M.; Morphet, D. R.; Reynolds, K. G.; Kudisch, B.; Gonzalez, M. I.; Zheng, S.-L.; Dogutan, D. K.; Nocera, D. G. Inorg. Chem. Commun. 2022, 146, 109999.

40

Templated Growth of a Spin-Frustrated Cluster Fragment of MnBr2 in a Metal–Organic Framework
Turkiewicz, A. B; Tomlinson, W.; Gonzalez, M. I.; Hooper, J.; Long, J. R. Inorg. Chem. 2021, 60, 16103–16110.

39

How Radical are "Radical" Photocatalysts? A Closed-Shell Meisenheimer Complex is Identified as a Super-reducing Photoreagent
Rieth, A.; Gonzalez, M. I.; Kudisch, B.; Nava, M. J.; Nocera, D. G. J. Am. Chem. Soc. 2021, 143, 14352–14359.

38

Fluoroarene Separations in Metal–Organic Frameworks with Two Proximal Mg2+ Coordination Sites
Zick, M. E.; Lee, J.-H.; Gonzalez, M. I.; Velasquez, E. O.; Uliana, A. A.; Kim, J.; Long. J. R.; Milner, P. J. J. Am. Chem. Soc. 2021, 143, 1948–1958.

37

Network-Forming Liquids from Metal–Bis(acetamide) Frameworks with Low Melting Temperatures
Liu, M.; McGillicuddy, R. D.; Vuong, H.; Tao, S.; Slavney, A. H.; Gonzalez, M. I.; Billinge, S. J. L.; Mason, J. A. J. Am. Chem. Soc. 2021, 143, 2801–2811.

36

Metal–Organic Phase-Change Materials for Thermal Energy Storage
McGillicuddy, R. D.; Thapa, S.; Wenny, M. B.; Gonzalez, M. I.; Mason, J. A. J. Am. Chem. Soc. 2020, 142, 19170–19180.

35

Influence of Pore Size on Carbon Dioxide Diffusion in Two Isoreticular Metal–Organic Frameworks
Forse, A. C.; Colwell, K. A.; Gonzalez, M. I.; Benders, S.; Torres-Gavosto, R. M.; Blümich, B.; Reimer, J. A.; Long, J. R. Chem. Mater. 2020, 32, 3570–3576.

34

Substituent effects on Exchange Coupling and Magnetic Relaxation in 2,2′-Bipyridine Radical-Bridged Dilanthanide Complexes
Gould, C. A.; Mu, E.; Vieru, V.; Darago, L. E.; Chakarawet, K.; Gonzalez, M. I.; Demir, S.; Long, J. R. J. Am. Chem. Soc. 2020, 142, 21197–21209.

33

Double Hangman Iron Porphyrin and the Effect of Electrostatic Nonbonding Interaction on Carbon Dioxide Reduction
Margarit, C. G.; Asimow, N. G.; Gonzalez, M. I., Nocera, D. G. J. Phys. Chem. Lett. 2020, 11, 1890–1895

32

Crystallographic characterization of the metal–organic framework Fe2(bdp)3 upon reductive cation insertion
Biggins, N.; Ziebel, M. E.; Gonzalez, M. I.; Long, J. R. Chem. Sci. 2020, 11, 9173–9180.

31

Multielectron C–H photoactivation with an Sb(V) oxo corrole
Lemon, C. M.; Maher, A. G.; Mazzotti, A. R.; Powers, D. C.; Gonzalez, M. I.; Nocera, D. G. Chem. Commun. 2020, 56, 5247–5250.

30

Thermodynamic Separation of 1-Butene from 2-Butene in Metal–Organic Frameworks with Open Metal Sites
Barnett, B. R.; Parker, S. T.; Paley, M. V.; Gonzalez, M. I.; Biggins, N.; Oktawiec, J.; Long, J. R. J. Am. Chem. Soc. 2019, 141, 18325–18333.

29

Recent progress towards light hydrocarbon separations using metal–organic frameworks
Barnett, B. R.; Gonzalez, M. I.; Long, J. R. Trends in Chemistry, 2019, 1, 159–171.

28

Elucidating CO2 Chemisorption in Diamine-Appended Metal–Organic Frameworks
Forse, A. C.; Milner, P. J.; Lee, J.-H.; Redfearn, H. N.; Siegelman, R. L.; Martell, J. D.; Dinakar, B.; Porter-Zasada, L. B.; Gonzalez, M. I.; Neaton, J. B.; Long, J. R.; Reimer, J. A. J. Am. Chem. Soc. 2018, 140, 18016–18031.

27

Cooperative adsorption carbon disulfide in diamine-appended metal–organic frameworks
McGuirk, C. M.; Siegelman, R. L.; Drisdell, W. S.; Runčevski, T.; Milner, P. J.; Oktawiec, J.; Wan, L. F.; Su, G. M.; Jiang, H. Z. H.; Reed, D. A.; Gonzalez, M. I.; Prendergast, D.; Long, J. R. Nat. Commun. 2018, 9, 5133.

26

Separation of Xe and Kr in Metal–Organic Frameworks M2(m-dobdc) (M = Co, Ni)
Kapelewski, M. T.; Oktawiec, J.; Runčevski, T; Gonzalez, M. I.; Long, J. R. Isr. J. Chem. 2018, 58, 1138–1143.

25

A Single Terminal Fluoride Ligand Generates Dysprosium Complexes with Highly Axial Magnetic Anisotropy
Norel, L.; Darago, L. E.; Le Guennic, B.; Chakarawet, K.; Gonzalez, M. I.; Olshansky, J. H.; Alivisatos, P.; Rigaut, S.; Long, J. R. Angew. Chem., Int. Ed. 2018, 57, 1933–1938.

24

Unexpected Diffusion Anisotropy of Carbon Dioxide in the Metal–Organic Framework Zn2(dobpdc)
Forse, A. C.; Gonzalez, M. I.; Siegelman, R. L.; Witherspoon V.; Milner, P. J.; Martell, J. D.; Blümich, B.; Long, J. R.; Reimer, J. A. J. Am. Chem. Soc. 2018, 5, 1663–1673.

23

Slow Magnetic Relaxation in a Dysprosium Ammonia Metallocene Complex
Demir, S.; Boshart, M. D.; Corbey, J. F.; Woen, D. H.; Gonzalez, M. I.; Ziller, J. W.; Meihaus, K. R.; Long, J. R.; Evans, W. J. Inorg. Chem. 2017, 56, 15049–15056.

22

Enantioselective Recognition of Ammonium Carbamates in a Chiral Metal–Organic Framework with High Surface Area and Stability
Martell, J. D.; Porter-Zasada, L. B.; Forse, A. C.; Siegelman, R. L.; Gonzalez, M. I.; Oktawiec, J.; Runčevski, T; Xu, J; Srebo-Hooper, M.; Milner, P. J.; Colwell, K. A.; Autschbach, J.; Reimer, J. A.; Long., J. R. J. Am. Chem. Soc. 2017, 139, 16000–16012.

21

M2(m-dobdc) (M = Mn, Fe, Co, Ni) Metal–Organic Frameworks as Highly-Selective, High-Capacity Adsorbents for Olefin/Paraffin Separations
Bachman J. E.†; Kapelewski, M. T.†; Reed, D. A.; Gonzalez, M. I.; Long, J. R. J. Am. Chem. Soc. 2017, 139, 15363–15370.

20

Calcium Coordination Solids for pH-Triggered Release of Olsalazine
Levine, D. J.; Gonzalez, M. I.; Legendre, C. M.; Runčevski, T.; Oktawiec, J.; Colwell, K. A.; Long, J. R. ChemMedChem. 2017, 12, 1739–1742.

19

A Diaminopropane-Appended Metal–Organic Framework Enabling Efficient CO2 Capture from Coal Flue Gas via a Mixed Adsorption Mechanism
Milner, P. J.; Siegelman, R. L.; Forse, A.; Gonzalez, M. I.; Runčevski, T.; Martell, J. D.; Reimer, J. A.; Long, J. R. J. Am. Chem. Soc. 2017, 139, 13541–13553.

18

Controlling Cooperative CO2 Adsorption in Diamine-Appended Mg2(dobpdc) Metal–Organic Frameworks
Siegelman, R. L.; McDonald, T. M.; Gonzalez, M. I.; Martell, J. D.; Milner, P. J.; Mason, J. A.; Berger, A. H.; Bhown, A. S.; Long, J. R. J. Am. Chem. Soc. 2017, 139, 10526–10538.

17

16

Metal Insertion in a Methylamine-Functionalized Zirconium Metal–Organic Framework for Enhanced Carbon Dioxide Capture
Gómora-Figueroa, A. P.; Mason, J. A.; Gonzalez, M. I.; Bloch, E. D.; Meihaus, K. R. Inorg. Chem. 2017, 56, 4308–4316.

15

A Trinuclear Radical-Bridged Lanthanide Single-Molecule Magnet
Gould, C. A.; Darago, L. E.; Gonzalez, M. I.; Demir, S.; Long, J. R. Angew. Chem., Int. Ed. 2017, 129, 10237–10241.

14

Tuning the Adsorption-Induced Phase Change in the Flexible Metal–Organic Framework Co(bdp)
Taylor, M. K.; Runčevski, T.; Oktawiec, J.; Gonzalez, M. I.; Siegelman, R. L.; Mason, J. A.; Ye, J.; Brown, C. M.; Long, J. R. J. Am. Chem. Soc. 2016, 138, 15019–15026.

13

Selective, Tunable O2 Binding in Cobalt(II)-Triazolate/Pyrazolate Metal–Organic Frameworks
Xiao, D. J.; Gonzalez, M. I.; Darago, L. E.; Vogiatzis, K. D.; Haldoupis, E.; Gagliardi, L.; Long, J. R. J. Am. Chem. Soc. 2016, 138, 7161–7170.

12

Reversible CO Scavenging via Adsorbate-Dependent Spin State Transitions in an Iron(II)-Triazolate Metal–Organic Framework
Reed, D. A.; Xiao, D. J.; Gonzalez, M. I.; Darago, L. E.; Herm, Z. R.; Grandjean, F.; Long, J. R. J. Am. Chem. Soc. 2016, 138, 5594–5602.

11

Hydrogen Storage in the Expanded Pore Metal–Organic Frameworks M2(dobpdc) (M = Mg, Mn, Fe, Co, Ni, Zn)
Gygi, D.; Bloch, E. D.; Mason, J. A.; Hudson, M. R.; Gonzalez, M. I.; Siegelman, R. L.; Darwish, T. A.; Queen, W. L.; Brown, C. M.; Long, J. R. Chem. Mater. 2016, 28, 1128–1138.

10

9

Synthesis and Characterization of a Tetrapodal NO44– Ligand and Its Transition Metal Complexes
Axelson, J. C.; Gonzalez, M. I.; Meihaus, K. R.; Chang, C. J.; Long, J. R. Inorg. Chem. 2016, 55, 7527–7534.

8

Force Field Development from Periodic Density Functional Theory Calculations for Gas Separation Applications Using Metal–Organic Frameworks
Mercado, R.; Vlaisavljevich, B.; Lin, L.-C.; Lee, K.; Lee, Y.; Mason, J. A.; Xiao, D. J.; Gonzalez, M. I.; Kapelewski, M. T.; Neaton, J. B.; Smit, Berend. J. Phys. Chem. C 2016, 120, 12590–12604.

7

Ruthenium Metal–Organic Frameworks with Different Defect Types: Influence on Porosity, Sorption, and Catalytic Properties
Zhang, W.; Kauer, M.; Halbherr, O.; Epp, K.; Guo, P.; Gonzalez, M. I.; Xiao, D. J.; Wiktor, C.; LIabrés i Xamena, F. X.; Wöll, C.; Wang, Y.; Muhler, M.; Fischer, R. A. Chem. Eur. J. 2016, 22, 14297–14307.

6

Methane Storage in Flexible Metal-Organic Frameworks with Intrinsic Thermal Management
Mason, J. A.; Oktawiec, J.; Taylor, M. K.; Hudson, M. R.; Rodriguez, J.; Bachman, J. E.; Gonzalez, M. I.; Cervellino, A.; Guagliardi, A.; Brown, C. M.; Llewellyn, P. L.; Masciocchi, N.; Long, J. R. Nature 2015, 527, 357–361.

5

Electronic Conductivity, Ferrimagnetic Ordering, and Reductive Insertion Mediated by Organic Mixed-Valence in a Ferric Semiquinoid Metal–Organic Framework
Darago, L. E.; Aubrey, M. L.; Yu, C. J.; Gonzalez, M. I.; Long, J. R. J. Am. Chem. Soc. 2015, 137, 15703–15711.

4

Comprehensive Study of Carbon Dioxide Adsorption in the Metal–Organic Frameworks M2(dobdc) (M = Mg, Mn, Fe, Ni, Cu, Zn)
Queen, W. L.; Hudson, M. R.; Bloch, E. D.; Mason, J. A.; Gonzalez, M. I.; Lee, J. S.; Gygi, D.; Howe, J. D.; Lee, K.; Darwish, T. A.; James, M.; Peterson, V. K.; Teat, S. J.; Smit, B.; Neaton, J. B.; Long, J. R.; Brown, C. M. Chem. Sci. 2014, 5, 4569–4581.

3

2

Tristability in a Light Actuated Single-Molecule Magnet
Feng, X.; Mathoniere, C.; Jeon, I.; Rouzieres, M.; Ozarowski, A.; Aubrey, M. L.; Gonzalez, M. I.; Clerac, R.; Long, J. R. J. Am. Chem. Soc. 2013, 135, 15880–15884.

1

†These authors contributed equally.